Evaluation of the relative roles of global versus local sedimentary controls on Middle to Late Pleistocene formation of continental margin strata,Canterbury Basin,New Zealand

Determining the relative influence of eustasy versus local sedimentary processes on strata formation is a fundamental challenge in the study of continental margin stratigraphy. In this paper, the relative contribution of these factors on continental margin evolution during the Middle to Late Pleistocene is evaluated using samples from Integrated Ocean Drilling Program Expedition 317. Core‐logging, biostratigraphy and quantitative X‐ray diffraction mineralogy are used to delineate continental shelf sedimentary systems. Major lithological unconformities bound stratigraphic sequences that contain recurring compositional patterns and that resemble other examples of Middle to Upper Pleistocene sequences. However, a preliminary chronology suggests that sequence boundary formation cannot be linked ‘one to one’ with eustatic cycles and therefore these sequences can contain multiple ca 100 ka eustatic cycles. Smaller amplitude, higher frequency transitions in sediment composition are interpreted as stratigraphic sequences driven by more rapid perturbations in the interplay of accommodation and sediment supply; their stratigraphy is variable in time and across the shelf, suggesting a strong influence of local sedimentary forcing in their formation. Changes in sediment composition after the Middle Pleistocene Transition indicate that sediment transfer from onshore sources in the glaciated Southern Alps to the middle‐shelf occurred over a single 100 ka glacio‐eustatic cycle, with an additional 100 ka lag before the mineralogical signal was preserved on the outer‐shelf. This phenomenon is coincident with rapid shelf progradation in this basin, suggesting a causal relation between across‐shelf sediment transport and margin progradation. This is one of very few studies that provide insights at the core scale into the processes driving continental margin evolution during the Middle to Late Pleistocene. This work shows that compositional changes in mud‐dominated successions can lead to a sequence stratigraphic interpretation and the identification of high‐frequency sequences, which may not be possible using a conventional stratigraphic approach.     

Mid-level clouds over the Sahara in a convection-permitting regional model

Climate Dynamics - The simulation of Saharan mid tropospheric clouds is investigated with the weather research and forecasting (WRF) regional atmospheric model at convection permitting...     

The Total Irradiance Monitor (TIM): Instrument Design

The Total Irradiance Monitor (TIM) instrument is designed to measure total solar irradiance with an absolute accuracy of 100 parts per million. Four electrical substitution radiometers behind precision apertures measure input radiant power while providing redundancy. Duty cycling the use of the radiometers tracks degradation of the nickel-phosphorous absorptive black radiometer interiors caused by solar exposure. Phase sensitive detection at the shutter frequency reduces noise and simplifies the estimate of the radiometer's equivalence ratio. An as-designed uncertainty budget estimates the instrument's accuracy goal. The TIM measurement equation defines the conversion from measured signal to solar irradiance.     

A survey of orbits of co-orbitals of Mars

Many asteroids with a semimajor axis close to that of Mars have been discovered in the last several years. Potentially some of these could be in 1:1 resonance with Mars, much as are the classic Trojan asteroids with Jupiter, and its lesser-known horseshoe companions with Earth. In the 1990s, two Trojan companions of Mars, 5261 Eureka and 1998 VF₃₁, were discovered, librating about the L₅ Lagrange point, 60° behind Mars in its orbit. Although several other potential Mars Trojans have been identified, our orbital calculations show only one other known asteroid, 1999 UJ₇, to be a Trojan, associated with the L₄ Lagrange point, 60° ahead of Mars in its orbit. We further find that asteroid 36017 (1999 ND₄₃) is a horseshoe librator, alternating with periods of Trojan motion. This asteroid makes repeated close approaches to Earth and has a chaotic orbit whose behavior can be confidently predicted for less than 3000 years. We identify two objects, 2001 HW₁₅ and 2000 TG₂, within the resonant region capable of undergoing what we designate “circulation transition”, in which objects can pass between circulation outside the orbit of Mars and circulation inside it, or vice versa. The eccentricity of the orbit of Mars appears to play an important role in circulation transition and in horseshoe motion. Based on the orbits and on spectroscopic data, the Trojan asteroids of Mars may be primordial bodies, while some co-orbital bodies may be in a temporary state of motion.     

Validating the Flash Code: Vortex-Dominated Flows

As a component of the Flash Center’s validation program, we compare FLASH simulation results with experimental results from Los Alamos National Laboratory. The flow of interest involves the lateral interaction between a planar M _a = 1.2 shock wave with a cylinder of gaseous sulfur hexafluoride (SF₆) in air, and in particular the development of primary and secondary instabilities after the passage of the shock. While the overall evolution of the flow is comparable in the simulations and experiments, small-scale features are difficult to match. We focus on the sensitivity of numerical results to simulation parameters.     

The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere

The production rate and isotopic composition of H₂ derived from radiolytic reactions in H₂O were measured to assess the importance of radiolytic H₂ in subsurface environments and to determine whether its isotopic signature can be used as a diagnostic tool. Saline and pure, aerobic and anaerobic water samples with pH values of 4, 7, and 10 were irradiated in sealed vials at room temperature with an artificial γ source, and the H₂ abundance in the headspace and its isotopic composition were measured. The H₂ concentrations were observed to increase linearly with dosage at a rate of 0.40 ± 0.04 molecules (100 eV)⁻¹ within the dosage range of 900 to 3500 Gray (Gy; Gy = 1 J Kg⁻¹) with no indication of a maximum limit on H₂ concentration. At ∼2000 Gy, the H₂ concentration varied only by 16% across the experimental range of pH, salinity, and O₂. Based upon this measured yield and H₂ yields for α and β particles, a radiolytic H₂ production rate of 10⁻⁹ to 10⁻⁴ nM s⁻¹ was estimated for the range of radioactive element concentrations and porosities typical of crustal rocks. The δD of H₂ was independent of the dosage, pH (except for pH 4), salinity, and O₂ and yielded an αD_H2O-H2 of 2.05 ± 0.07 (αD_H2O-H2 = (D/H)_H2O to (D/H)_H2), slightly less than predicted radiolytic models. Although this radiolytic fractionation value is significantly heavier than that of equilibrium isotopic exchange between H₂ and H₂O, the isotopic exchange rate between H₂ and H₂O will erase the heavy δD of radiolytic H₂ if the age of the groundwater is greater than ∼10³ to 10⁴ yr. The millimolar concentrations of H₂ observed in the groundwater of several Precambrian Shields are consistent with radiolysis of water that has resided in the subsurface for a few million years. These concentrations are well above those required to support H₂-utilizing microorganisms and to inhibit H₂-producing, fermentative microorganisms.     

Numerical experiments on the onset of convective instability in the Earth's mantle

Summary. A simplified model of convection in the mantle is used to investigate the transient effect of cooling a fluid layer from above, The model, representing the mantle overlain by the lithosphere, consists of a two-dimensional fluid layer overlain by a solid conducting lid. The initial temperature of both layers is the same, with the top surface of the lid kept at 0°C throughout. We observe the onset of small-scale flow in the model. In the absence of internal heating the behaviour of the system is controlled by the Rayleigh number, R , and the ratio of the thicknesses of the two layers, a . The onset time of convection as defined by reference to conduction temperature profiles is related simply to a boundary layer critical Rayleigh number. The mean temperature profiles for the convection model are also compared with the observed depth—age relation for oceanic lithosphere and the results are used to estimate the viscosity of the mantle.